The authors investigated the magnetic and ferroelectric properties of hexagonally grown HoMnO3 thin films. The magnetic measurements revealed bulklike magnetic phase transitions with an additional spin-glass-like behavior feature below the Neel temperature. The ferroelectricity in the films was distinctly different from the suggested bulk behavior. Below 40 K, the HoMnO3 films showed typical ferroelectric character: their remnant polarization and coercive field values at 20 K were 3.7 mu C/cm(2) and 0.69 MV/cm. Above 40 K, however, the films exhibited an unusual antiferroelectriclike behavior, with more pronounced features appearing at higher temperatures. These intriguing physical properties make HoMnO3 films a potential candidate material for numerous future applications.
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