期刊
INTERNATIONAL JOURNAL OF COAL GEOLOGY
卷 70, 期 1-3, 页码 223-239出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.coal.2006.05.001
关键词
methane sorption capacity; organic matter content; maccral content; microporosity; moisture content
The methane sorption capacity of a succession of sandstone, siltstone, shale and coal from the Lower Cretaceous Fort St John Group of Northeastern British Columbia was investigated. Average organic matter (OM) content for all formations is 2.3 wt.% with a minimum of 0.6 wt.% and maximum of 10.1 wt.%. The methane sorption capacity ranges between 0.19 and 2.74 cm(3)/g at 6 MPa and at 30 degrees C. Total gas capacity (free and sorbed gas) ranges between 2.2 and 16.6 cm(3)/g at 6 MPa. Micropore volumes range between 0.43 and 1.69 cm(3)/100 g. A positive correlation exists between the OM content, micropore volume and the methane capacity of shales. Shales with high methane capacities have either high contents of inertodetrinite or vitrinite. Moisture content shows a positive relationship with OM content, micropore volume and methane capacity. The negative relationship between moisture and surface area derived from N-2 adsorption suggests the moisture is located within the microporosity of the OM, and also explains the positive relationship between methane capacity and moisture. The high inertodetrinite and vitrinite contents correlate with sea-level regressions that delivered terrestrial OM from coastal plains located south of the study area into the basin. (c) 2006 Elsevier B.V. All rights reserved.
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