期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 13, 页码 3798-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja069171f
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We report a new gold-catalyzed deoxygenated cyclization of cis-2,4-dien-1-als with external nucleophiles at ambient temperatures, which leads to a 1,4-double nucleophilic addition to the newly formed cyclopentene ring. The use of this cyclization is reflected not only by its compatibility with a wide scope of nucleophiles, but also by a facile construction of complex frameworks in diversified approaches.
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