期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 13, 页码 3826-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja070265e
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资金
- NCI NIH HHS [CA 91904] Funding Source: Medline
Hetero-bis-metalated 1,3,5-hexatrienes are employed in the linchpin coupling of synthetic fragments for the convergent construction of the central pentaene of the antifungal agent 2'-O-methylmyxalamide D and its (6E) isomer. Sequential Stille and Suzuki-Miyaura couplings interpolate the boron/tin triene into the pentaene chain. The total synthesis of O-methylmyxalamide D and its (6E) isomer was accomplished efficiently.
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