期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 14, 页码 4160-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja070789e
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资金
- NIGMS NIH HHS [R01 GM073932-01] Funding Source: Medline
A series of gold(I)-catalyzed rearrangement reactions of alkynyl sulfoxides are reported. Homopropargylsulfoxides are rearranged to benzothiepinones or benzothiopines, while alpha-thioenones are formed in the reaction of propargylsulfoxides. The proposed mechanism proceeds via an alpha-carbonyl gold-carbenoid intermediate formed through gold-promoted oxygen atom transfer from the sulfoxide to the alkyne.
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