期刊
PHYSICA B-CONDENSED MATTER
卷 392, 期 1-2, 页码 127-131出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.physb.2006.11.006
关键词
FTIR spectroscopy; primary alcohols; acrylic esters; hydrogen bonding
The molecular interaction between alkyl methacrylates (methyl methacrylate, ethyl methacrylate and butyl methacrylate) and primary alcohols (1-propanol, 1-butanot, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) has been studied in carbon tetrachloride by FTIR spectroscopic and dielectric methods. The results show that the most likely association between alcohol and ester is 1: 1 complex through the free hydroxyl group of the alcohol and the carbonyl group of ester, and the alkyl chain length of both the alcohols and esters plays an important role in the determination of the strength of hydrogen bond (O-H:O=C) formed. (c) 2006 Elsevier B.V. All rights reserved.
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