期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 28, 期 8, 页码 942-947出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200700030
关键词
fluorinated vinyl copolymers; functionalization of polymers; nonlinear optics; nonlinear polymers; second-harmonic generation
A new chromophore, C1, based on a similar D pi A-structure as in the FTC-chromophore but with a hydroxyalkyl spacer perpendicular to the direction of the dipole moment was synthesized. Both chromophores and the CLD-chromophore were used to prepare high T-g nonlinear optical vinyl polymers. The influence of the position of the spacer on the D pi A-system on the NLO response of the resulting polymers was investigated.
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