期刊
SYNTHESIS-STUTTGART
卷 -, 期 8, 页码 1247-1250出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-965971
关键词
catalysis; copper; cycloadditions; ionic liquids; photochemistry
Intra- and intermolecular copper(|I)-catalyzed [2+2] photocycloaddition reactions of nonconjugated alkenes can be achieved efficiently in room-temperature ionic liquids such as [tmba][NTf2]. The ionic liquid can be recovered and recycled. No cycloadduct could be isolated when the same reaction is carried out under identical conditions in [bmim][NTf2], which undergoes extensive decomposition.
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