4.4 Article

Domino reactions of 1,3-bis(silyl enol ethers) with 4-(trialkylsilyloxy)benzopyrylium triflates

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SYNLETT
卷 -, 期 7, 页码 1016-1025

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GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-973894

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cyclizations; domino reactions; heterocycles; pyrylium; salts; silyl enol ethers

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4-(Silyloxy)benzopyrylili.m triflates can be readily generated in situ by reaction of chromones with trialkylsilyl-trifluoromethanesulfonate. Domino reactions of silyl enol ethers with benzopyrylium triflates - derived from chromones, 3-cyanochromones and 3-formylchromones - allow an efficient synthesis of a variety of carba- and heterocycles.

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