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Boronated enynes as versatile sources of stereodefined and skeletally diverse molecules

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卷 9, 期 9, 页码 1717-1720

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AMER CHEMICAL SOC
DOI: 10.1021/ol070400s

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The application of a one-pot palladium-catalyzed cycloisomerization of enynes 1/Diels-Alder cycloaddition/allylboration sequence efficiently generates tricyclic structures with complete control of the four stereogenic centers. Ruthenium and platinum catalysts perform distinct transformations providing other isomeric boron-substituted cyclic compounds.

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