期刊
HETEROCYCLES
卷 71, 期 5, 页码 1107-1115出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-07-11014
关键词
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New approach to pyrimidinecarbonitriles was developed. Pyrimidine-4- and 6-carbonitriles were prepared by palladium-catalyzed cross-coupling reaction of iodopyrimidines with Zn(CN)2 in very good yields. The cyano group was converted into the corresponding acyl groups by the treatment with Grignard reagents and transformed to amido and imido function as well.
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