期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 349, 期 7, 页码 1025-1027出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700002
关键词
biaryls; cross-coupling; germanium; palladium
Powdery reagents obtained by complete alkaline hydrolysis of arylgermanium trichlorides were found to undergo the palladium-catalyzed cross-coupling reaction with aryl bromides and iodides in good yields. The reaction is performed in an aqueous medium taking sodium hydroxide as an activator. Some base-sensitive functionalities such as acetyl and trifluoromethyl groups survived the reaction.
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