期刊
CATALYSIS LETTERS
卷 115, 期 1-2, 页码 70-78出版社
SPRINGER
DOI: 10.1007/s10562-007-9075-z
关键词
autothermal reforming; n-dodecane; toluene; hydrocarbon mixture; zirconia; bimetallic; noble metal catalysts; DRIFTS; chemisorption; FT-IR
Autothermal reforming (ATR) of higher hydrocarbons and their mixture was studied on zirconia-supported mono- (Rh, Pd, or Pt) and bimetallic (RhPt) catalysts. ATR reactions predominated on Rh-containing catalysts at 700-900 degrees C, whereas thermal cracking predominated on Pt and the support. The thermal stability of Rh was improved when Rh was combined with Pt in the bimetallic catalyst.
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