4.7 Article

Electric double layer on fractal electrodes

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PHYSICAL REVIEW E
卷 75, 期 5, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.75.051502

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The electric double layer around fractal electrodes is studied with direct numerical simulations of the Nernst-Planck equation coupled with the Poisson equation. The capacitance and the relaxation time obey a power law as a function of the system size, the temperature, and the concentration. The time evolution of the charging process exhibits a stretched exponential law, and the exponent beta is numerically evaluated.

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