期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 90, 期 5, 页码 1401-1405出版社
BLACKWELL PUBLISHING
DOI: 10.1111/j.1551-2916.2007.01567.x
关键词
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Nonstabilized and silica-stabilized zirconia (ZrO2) crystallites with sizes between 3 and 4 nm were synthesized by a novel combined sol-gel and solvothermal process. After adding zirconium n-propoxide to a solution of isobutanol, propionic acid, and water, a transparent nanoparticulate sol was synthesized by a sol-gel process. The average hydrodynamic diameter of the amorphous ZrO2 nanoparticles was approximately 5 nm. A following solvothermal process led to a crystalline fraction of the powder consisting of 31 wt% tetragonal (t) phase ZrO2. This fraction was doubled to 61 wt% by adding 10 mol% 3-methacryloxypropyl trimethoxysilane (MPTS) and increased to 96 wt% by a subsequent calcination at 800 degrees C. The crystallite sizes were also confirmed by means of Brunauer-Emmett-Teller and high-resolution transmission electron microscopy.
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