Preparation and determination of spin-polarized states in multi-Zeeman-sublevel atoms

We demonstrate a simple, all-optical technique to prepare and determine the desired internal quantum states in multi-Zeeman-sublevel atoms. By choosing appropriate coupling and pumping laser beams, atoms can be easily prepared in a desired Zeeman sublevel with high purity or in any chosen ground-state population distributions (spin-polarized quantum-state engineering). The population distributions or state purities of such prepared atomic states can be determined by using a weak, circularly polarized probe beam due to differences in transition strengths among different Zeeman sublevels. This technique will have potential impact on quantum-information processing in multilevel atomic systems.