期刊
POLYMER DEGRADATION AND STABILITY
卷 92, 期 6, 页码 1141-1150出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2007.01.031
关键词
degradation mechanism; UV/moisture dual-curing; flame retardant; coating
A novel silicone and phosphate modified acrylate (DGTH) was synthesized and characterized by H-1 NMR and FTIR. It was found that DGTH could be cured both by UV radiation and moisture mode with FTIR. The flammability and thermal behavior of the cured film were studied by the limited oxygen index (LOI), thermogravimetric analysis (TG) and real time Fourier transform infrared (RT-FTIR). The LOI value of the cured film is 48 and the TG data shows that the cured film has three characteristic degradation temperature regions, attributing to the decomposition of phosphate and polyurethane to alcohols and isocyanates, thermal pyrolysis of alkyl chains, and decomposition of unstable structures in char, respectively. The RT-FTIR data implies that the degraded products of phosphate form poly(phosphoric acid) further catalyse the breakage of carbonyl groups to form an intumescent char, preventing the samples from further burning. (c) 2007 Published by Elsevier Ltd.
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