期刊
CHINESE CHEMICAL LETTERS
卷 18, 期 6, 页码 625-628出版社
CHINESE CHEMICAL SOCIETY
DOI: 10.1016/j.cclet.2007.04.014
关键词
palladium catalyst; Suzuki reaction; Heck reaction; phosphine-free ligand
Some 1,3-dicarbonyl compounds (such as pentane-2,4-dione and 3-oxo-N-phenylbutanamide) were found to constitute highly efficient, yet low-priced and phosphine-free ligands for the Pd-catalyzed Heck and Suzuki reactions of aryl bromides and iodides with very high turnover numbers (ca. 10(3)-10(4)). (C) 2007 Qing Xiang Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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