期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2007, 期 16, 页码 2575-2600出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200700032
关键词
total synthesis; natural products; organocatalysis; medicinal chemistry; asymmetric synthesis
Catalytic reactions are a key element in the design of sustainable chemical processes. As witnessed in the field of transition metal-catalysed processes, only those reactions that are reliable over a broad substrate range and tolerant toward a multitude of functional groups have found their way into the repertoire of preparative chemists. Natural product synthesis provides a good benchmark for the maturity of a new synthetic method and in this microreview we discuss the scope and limitations of organocatalytic reactions in the synthesis of biologically important molecules. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
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