期刊
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
卷 43, 期 6, 页码 737-741出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1023193507060183
关键词
substituted bismuth vanadate; oxygen-ion conductor; structure; electrical conduction
Conditions for synthesizing single-phase solid solutions Bi4V2-xCux/2Tix/2O11 - x and Bi4 - x/2V2 - x/2Cux/2Tix/2O11 - x/2 are studied. The sequence of phase transformations is determined. Possible domains of stability of polymorphic modifications and the overall conductivity as a function of temperature and composition are studied. The structure of the gamma-modification is refined using Rietveld's full-profile analysis.
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