期刊
ANALYTICAL SCIENCES
卷 27, 期 7, 页码 757-763出版社
JAPAN SOC ANALYTICAL CHEMISTRY
DOI: 10.2116/analsci.27.757
关键词
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Fast and selective sorptions of Cr(VI) species from aqueous media onto tetraphenylphosphonium bromide (TPP+center dot Br-) physically immobilized polyurethane foams (PUFs) sorbent were achieved. Based on the Scatchard model of binding sites of the PUFs and Langmuir and Dubinin-Radushkevich (D-R) adsorption models of Cr(VI) retention onto TPP+center dot Br- immobilized PUFs, a dual retention mechanism involving absorption related to weak-base anion ion exchange and an added component for surface adsorption was proposed. Thus, the TPP+center dot Br- loaded PUFs were successfully packed in column mode for preconcentration of trace and ultra trace concentrations of Cr(VI) as halochromates [CrO3C](-)(aq) from aqueous HCl media. The retained [CrOCl3](-)(aq) species were recovered with NaOH (1.0 mol L-1) and analyzed by flame atomic absorption spectrometry. Cr(111) species after oxidation to Cr(VI) with H2O2 in aqueous KOH (1.0 mol L-1) were also retained and could be recovered by the proposed method. The limits of detection (LOD) and quantification (LOQ) of Cr(VI) were 0.04 and 0.13 mu g L-1, respectively. The chemical speciation of Cr(III, VI) species in various water samples at trace and ultra trace levels were carried out by TPP+center dot Br- loaded PUFs packed column. The enhancement factor and sensitivity factor of [CrO3C](-)(aq) sorption were 80.0 and 30.0, respectively.
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