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Application of Ionic Liquids for Solid-Phase Extraction of Trace Elements

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ANALYTICAL SCIENCES
卷 24, 期 10, 页码 1351-1353

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JAPAN SOC ANALYTICAL CHEMISTRY
DOI: 10.2116/analsci.24.1351

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That phosphonium-type ionic liquids (ILs) can be used for preparation of novel solid-phase extractants has been shown. The conditions of IL immobilization on the different matrices (polyacrilonitrile, Amberlite XAD-7, hyper cross-linked polystyrene, and multi-walled carbon nanotubes) were determined. The solid-phase extraction of Pt(IV) from 1 - 2 M HCl and Pu(IV) from 3 M HNO3 has been investigated. The possibility of retaining ligands on the solid phases by means of ILs to prepare the complexing solid-phase extractants has been demonstrated.

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