Complex networks are mapped to a model of boxes and balls where the balls are distinguishable. It is shown that the scale-free size distribution of boxes maximizes the information associated with the boxes provided configurations including boxes containing a finite fraction of the total amount of balls are excluded. It is conjectured that for a connected network with only links between different nodes, the nodes with a finite fraction of links are effectively suppressed. It is hence suggested that for such networks the scale-free node-size distribution maximizes the information encoded on the nodes. The noise associated with the size distributions is also obtained from a maximum entropy principle. Finally, explicit predictions from our least bias approach are found to be borne out by metabolic networks.(c) 2007 American Institute of Physics.
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