期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 692, 期 13, 页码 2608-2632出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2007.02.036
关键词
organometallics; intramolecular; five-membered ring; organic synthesis; catalysts; applications; cyclo-metalation
There are three types of reactions with intramolecular five-membered ring compounds in organic syntheses: The first type is reactions involving intramolecular five-membered ring compounds which are utilized for the ease of synthesis of these compounds and the stability of the products. The second is reactions performed via intramolecular five-membered ring intermediates, because such intermediates are very reactive and labile compounds. The third is the metal-catalyzed reactions with the intramolecular five-membered ring compounds because these metal compounds have catalytic activities. The third type reactions involving intramolecular five-membered ring pincer compounds are also provided. The first type reactions include carbonylations, alkenylations, alkynylations, acylations, isocyanations, Diels-Alder reactions, etc. The second type reactions include carbonylations, cross-coupling reactions, hydroacylations, ring expansion reactions, carbocyclizations, etc. The third type reactions include cross-coupling reactions, rearrangements, metatheses, reductions, Michael reactions, dehydrogenations, Diels-Alder reactions, etc. (c) 2007 Elsevier B.V. All rights reserved.
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