期刊
ANALYTICAL LETTERS
卷 46, 期 8, 页码 1183-1197出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00032719.2012.755687
关键词
Environmental waters; High performance liquid chromatography; Magnetic chitosan; Pyrethroids
资金
- Fundamental Research Funds for the Central Universities [DL10DB01]
The magnetic chitosan was prepared by adding chitosan, Fe2+ and Fe3+ into a basic precipitant of NaOH solution. The synthetic magnetic chitosan was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and physical properties. The adsorption characteristics of magnetic chitosan for extracting pyrethroids from water samples were investigated. The analytes were separated by magnetic solid phase extraction and determined by high performance liquid chromatography. The optimum conditions of adsorption experiments were obtained: the amount of sorbent was 80mg, the extraction time was 20min, the washing solvent was 50% aqueous methanol, and the eluent was acetonitrile-acetic acid (99: 1, v/v). The obtained linearity of three pyrethroids was in the range of 303000ngL(1). The detection limits of beta-cyfluthrin, cyhalothrin, and cyphenothrin were 7.5, 5.6, and 6.1ngL(1), respectively. The intra-day and inter-day precisions of three pyrethroids were in the range of 3.65.2% and 5.98.6%, respectively. In the optimized conditions, three water samples were analyzed, and the recoveries of pyrethroids obtained were 83.295.2%.
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