期刊
ANALYTICAL LETTERS
卷 46, 期 6, 页码 969-981出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00032719.2012.745085
关键词
Acrylamide; ATRP; Graphite oxide; Molecular imprinted polymers; Molecular recognition
资金
- 973 National Basic Research Program of China [2012CB720804]
- National research program [2011BAK10B03, 201203069-1, 201003008-08-03]
- Fundamental Research Funds for the Central Universities [JUSRP21101]
A novel acrylamide (AA) molecularly imprinted polymer was synthesized by atom transfer radical polymerization (ATRP) on graphite oxide (GO) particles. Propionamide (PAM) was used as a dummy template molecule, hydroxy ethyl acrylate (HEA) as a functional monomer, ethylene glycol dimethacrylate (EDMA) as a crosslinking agent, and acetonitrile as both solvent and dispersion medium. Scanning electron microscopy (SEM) images and infrared spectroscopy (IR) confirmed that the molecularly imprinted polymers (MIP) were successfully grafted onto the surface of the GO particles. The corresponding adsorption kinetic curves and adsorption isotherms showed that the AA adsorption reached equilibrium after 5h, with large amounts of AA being adsorped in the first 100min. The maximum AA adsorption capacity was 123.48 mu mol g1 according to Scatchard analysis, which indicated that the MIP possesses good AA adsorption capacity. This MIP-GO material was used to selectively determine AA in fried food samples.
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