期刊
TETRAHEDRON LETTERS
卷 48, 期 23, 页码 4131-4134出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.03.172
关键词
titanocene(III) chloride; radical reaction; 3,4-dihydroisocournarins; hydrangenol
A radically promoted synthesis of 3,4-dihydroisocoumarins has been achieved in moderate to good yields using titanocene(III) chloride (Cp2TiCl) as the radical initiator. The total synthesis of (+/-)-hydrangenol has been completed using this radical technology. Cp2TiCl was prepared in situ from commercially available titanocene dichloride (Cp2TiCl2) and Zn-dust in THF under argon. (c) 2007 Elsevier Ltd. All rights reserved.
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