期刊
TETRAHEDRON LETTERS
卷 48, 期 23, 页码 4003-4005出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.04.039
关键词
allyl transfer; allylrhodium; carbon-carbon bond cleavage; retro-allylation
Retro-allylation of homoallyl alcohols by rhodium catalysts occurs to generate allylrhodium species. Insertion of acrylate esters to the allylrhodiums proceeds to give the corresponding 2,5-hexadienoate esters in situ. Subsequent isomerization or iterative 1,4-addition takes place in the same pots to furnish the corresponding 2,4-hexadienoate esters or triesters in good yields. (c) 2007 Elsevier Ltd. All rights reserved.
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