期刊
ANALYTICAL CHEMISTRY
卷 90, 期 19, 页码 11216-11218出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.analchem.8b02956
关键词
-
资金
- German Research Foundation [DY 81/5-1]
Earlier an automated sample preparation unit for inorganic nitrogen (SPIN) coupled to a membrane inlet quadrupole mass spectrometer (MIMS) was developed for automated and sensitive determination of the N-15 abundances and concentrations of nitrate, nitrite and ammonium of aqueous solutions without any sample preparation. Here we describe an alternative analytical protocol to convert NO3- to N2O instead of NO before measurement. This is advantageous because NO strongly interacts with surfaces, requires long purge times, and still shows considerable carryover between samples, all of which is avoided when N2O is used as analyte. The sensitivity of the measurement of NO3- as N2O is comparable to the earlier measurements with NO as analyte.
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