期刊
FORENSIC SCIENCE INTERNATIONAL
卷 169, 期 1, 页码 32-42出版社
ELSEVIER IRELAND LTD
DOI: 10.1016/j.forsciint.2006.07.024
关键词
designer drugs; alpha-pyrrolidinophenone substructure; structure elucidation; mass spectral data; product ion mass spectrometry; NMR spectroscopy
This study presents and discusses the nuclear magnetic resonance (NMR) spectroscopic and mass spectroscopic data of the new designer drug 4'-methyl-alpha-pyrrolidinobutyrophenone (MPBP) and its homolog 4'-methyl-alpha-pyrrolidinohexanophenone (MPHP) which were seized in 2004 and 2000 in Germany for the first time. The structure elucidation of the aliphatic part of MPBP was carried out by product ion spectroscopy of the immonium ion formed after electron ionization as well as with H-1 and C-13 NMR. Product ion spectroscopy of immonium ions again proved to be a powerful tool to deter-mine the structure of designer drugs and to distinguish between isobaric structures of the alkyl-amino moiety. (C) 2006 Elsevier Ireland Ltd. All rights reserved.
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