期刊
TETRAHEDRON LETTERS
卷 48, 期 25, 页码 4327-4330出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.04.108
关键词
marine alkaloid; barrenazine; amino acid; pyrazine synthesis
We report herein a concise and biomimetic synthesis of a precursor of barrenazine A, a cytotoxic alkaloid. The C2-symmetry of this molecule suggested the dimerization of an aminoketone, as the precursor of the central core pyrazine. This compound was prepared by assembly of aspartic acid and glycine. (c) 2007 Elsevier Ltd. All rights reserved.
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