期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 13, 页码 4837-4843出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo070530e
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资金
- NIGMS NIH HHS [T32 GM08785, GM47969] Funding Source: Medline
Here we report the stereo- and regiospecific C-6 alkylation of a trans-inden-5-one (from optically pure Hajos-Parrish ketone) with allylic electrophiles. Use of this alkylation procedure has led to an improved synthesis of the benz[f]indene ring system and the first enantiospecific total syntheses of the cyclopenta[b]anthracene and cyclopenta[b]phenanthrene ring systems (two synthetic routes).
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