期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 25, 页码 7718-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja071098l
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Pd-catalyzed asymmetric allylic alkylation reactions of acyclic ketones with monosubstituted allyl substrates using 1,1'-P,N-ferrocene with H as substituent on the oxazoline ring as ligand gave products having two chiral centers with high yields and with high regio-, diastereo-, and enantioselectivities, with the ratio of branched and linear products being 98:2, anti:syn ratio for branched products being 7-21:1, and ee for the anti-products being 92-99%.
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