期刊
ANALYTICAL CHEMISTRY
卷 85, 期 5, 页码 2601-2605出版社
AMER CHEMICAL SOC
DOI: 10.1021/ac303263n
关键词
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资金
- National Natural Science Foundation of China [20927007, 21175094, 21177090]
- Youth Foundation of Sichuan University [2010SCU11048]
In this paper, the anodic electrogenerated chemiluminescence (ECL) behavior of graphite-like carbon nitride (g-C3N4) is studied using cyclic voltammetry with triethanolamine (TEA) as a coreactant. The possible anodic ECL response mechanism of the g-C3N4/TEA system is proposed. Furthermore, it is observed that the anodic ECL signal can be quenched efficiently in the presence of rutin, on the basis of which a facile anodic ECL senor for the determination of rutin is developed. This ECL sensor is found to have a linear response in the range of 0.20-45.0 mu M and a low detection limit of 0.14 mu M (at signal-to-noise of 3). These results suggest that semiconductor g-C3N4 has great potential in extending the application in the ECL field as an efficient luminophore.
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