期刊
COORDINATION CHEMISTRY REVIEWS
卷 251, 期 13-14, 页码 1734-1746出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.01.001
关键词
thiacalix[n]arene; sulfinylcalix[4]arene; sulfonylcalix[4]arene; transition metal; lanthanide; cluster
This review deals with the formations, structures, and properties of transition metal and lanthanide clusters supported by thiacalix[n]arene and its oxidized derivatives, sulfinylcalix[4]arene and sulfonylcalix[4]arene. Each thiacalix[n]arene possesses donor atoms both on the lower rim position (phenol oxygen atoms) and on the cyclic framework itself (-S-, -SO-, or -SO2-), and behaves as a multidentate multi-nucleating ligand to support the formation of a phenoxo-bridged cluster core. For first row transition metals, calix[4]arenes offer a platform for assembling the metal ions via four fac-tridentate coordination sites, and planar tri- and tetra-nuclear clusters are formed. A larger and more flexible thiacalix[6]arene could bind up to five metal ions inside the coordination cavity formed when it adopts the pinched cone conformation. Sulfonylcalix[4]arene shows a strong affinity to lanthanide ions through phenoxo and sulfonyl oxygen donors, and yields a variety of cluster compounds involving di-, tetra-, octa-, and dodeca-nuclear cores, achieved by controlled synthetic conditions. (C) 2007 Elsevier B.V. All rights reserved.
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