期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 349, 期 10, 页码 1671-1675出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600525
关键词
chiral auxiliaries; direct condensation; nanocrystalline magnesium oxide; selectivity; solvent-free conditions; unsymmetrical organic carbonates
An efficient and selective synthesis of organic carbonates using nanocrystalline magnesium oxide has been realized by the direct condensation of alcohols and diethyl carbonate. The catalyst is quantitatively recovered by simple centrifugation and can be reused for four cycles with almost consistent activity.
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