Mobilization and re-distribution of major and trace elements during extreme weathering of basalt in Hainan Island, South China

Major, trace and organic elements of a laterite profile developed on Neogene basalts in northern Hainan Island, South China were reported in this paper, the aim of which was to investigate element mobilization and re-distribution during extreme weathering. The results indicate that most of the elements have been mobilized and transferred downwards along the profile by aqueous solution. Organic matter (OM) can significantly improve the transport of insoluble elements. Among all the elements, Th is the least mobile. As for the general conservative elements during incipient chemical weathering, such as Fe, Ti, Zr, Hf, Nb and Ta, the removals are up to 20-40% in the upper profile. However, these elements behave as conservatively as Th in the lower profile. In the middle profile, oxic environment occurs, accompanied with significant OM decomposition. The Mn and Cc transferred downward are readily oxidized into insoluble Mn(IV) and Ce(IV) and precipitate in the oxic front. Important OM decomposition decreases the capacity of transfer of insoluble elements in aqueous solution. Consequently, Al significantly precipitates in the oxic front, and REEs, with the exception of Ce, precipitate largely in the OM-depleted layers. Co and U are also concentrated in the oxic front in association with Mn and Ce, respectively. However, Cr shows a negative correlation with Mn because its response to redox condition changes is reversed from that of Mn. Mn oxides/hydroxides, Fe oxides/hydroxides and secondary phosphate minerals other than clay minerals are potential hosts for REEs except for Cc in the profile; REEs with high concentrations in the profile seem closely associated with Mn oxides/hydroxides. Remarkable, highly correlated, Cc and Gd anomalies are observed in the profile. Cc anomalies are caused by Ce precipitation in the oxic environment and successive decomposition of organic matter. Gd anomalies are likely to have resulted from lower stability constants of Gd-OM complexes compared to those of neighboring REEs. The overall elemental behaviors in this profile suggest that organic matter plays a very important role in the mobilization and re-distribution of the elements during extreme weathering. (c) 2007 Elsevier Ltd. All rights reserved.