期刊
ANALYTICAL CHEMISTRY
卷 82, 期 17, 页码 7380-7386出版社
AMER CHEMICAL SOC
DOI: 10.1021/ac101510b
关键词
-
资金
- National Natural Science Foundation of China [20935002, 90813015]
In this paper, Mn-doped ZnS quantum dots (QDs) capped by a molecularly imprinted polymer (MIP) were synthesized. The results showed a high selectivity of the MIP-capped Mn-doped ZnS QDs toward the template molecule (4-nitrophenol) by QD fluorescence quenching. The application of MIP-capped Mn-doped ZnS QDs to the chemiluminescence (CL) system was also studied using a KIO4-H2O2 system. This application combines the good selectivity of MIP with the high sensitivity of CL. The linear range of this CL system is from 0.1 to 40 mu M, and the detection limit (DL) for 4-nitrophenol in the water can reach 76 nM. The method was also used in the real water samples, and the recoveries can fall in the range of 91-96%.
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