期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2007, 期 19, 页码 3077-3089出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200601050
关键词
allylic alcohol; allylic amine; allylation; palladium; promoter; reaction mechanisms
This review describes the different Pd-catalyzed methods that afford allylic amines from intermolecular reactions between allylic alcohols and amines and, with personal comments, the mechanisms that have been proposed. Allylic amines are an important class of compounds, while a wide structural variety of allylic alcohols are commercially available and are abundant in nature. The advantages of the use of allylic alcohols over that of their derivatives such as allylic esters or carbonates are the high atom efficiency and the formation only of water as the by-product.
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