期刊
KINETICS AND CATALYSIS
卷 48, 期 4, 页码 521-534出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0023158407040088
关键词
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The potential of high-resolution solid-state NMR spectroscopy for kinetic and mechanistic studies of hydrocarbon conversion on solid acid catalysis between 20 and 300 degrees C is considered. The use of this technique is illustrated by the elucidation of the mechanisms of hydrogen exchange and C-13 label transfer in alkanes and olefins, n-butane isomerization on sulfated zirconia, and ethane aromatization on zinc-containing zeolite beta. The kinetic parameters determined in these studies provide a basis for quantum chemical calculations of possible hydrocarbon activation and conversion pathways and for evaluating the reliability and accuracy of these theoretical calculations.
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