期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 692, 期 15, 页码 3212-3222出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2007.01.051
关键词
atom transfer radical polymerization; electron transfer; disproportionation; radical coordination
The continuous development of more active and stable catalysts in atom transfer radical polymerization (ATRP) has increasingly required a thorough knowledge of concurrent electron transfer reactions that can affect catalyst performance. Special attention is provided in this short review to such processes, including disproportionation, most pronounced in Cu-mediated ATRP, the reduction of radicals to carbanions or oxidation to carbocations, and radical coordination to the metal catalyst resulting in the interplay of controlled radical polymerization mechanisms. (c) 2007 Elsevier B.V. All rights reserved.
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