期刊
TETRAHEDRON
卷 63, 期 27, 页码 6306-6316出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.02.122
关键词
gold; platinum; enynes; cyclizations; rearrangements
Cyclopropyl metal carbenes formed in the 6-endo-dig cyclization may evolve to form seven-membered ring intermediates. This has been achieved for the first time by using highly electrophilic platinum(II) and gold(I) complexes. Gold(I) also triggers a remarkable rearrangement of certain enynes leading to complex cyclic systems. A new cationic platinacycle is described, which catalyzes skeletal rear-rangements and other reactions of enynes at room temperature. (c) 2007 Elsevier Ltd. All rights reserved.
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