期刊
SYNLETT
卷 -, 期 11, 页码 1771-1774出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-984500
关键词
C-C coupling; gold; Suzuki; Sonogashira; homogeneous catalysis; heterogenized
Recycling, of heterogenized gold(I), gold(III), and palladium(II) complexes Could be achieved for Suzuki and Sonogashira cross-coupling reaction between iodo benzene and arylboronic acids or alkynes. Au(I) and Pd(II) afford selectively nonsymmetrical biaryl compounds, while gold(III) complexes can only catalyze the arylboronic or alkynes homocoupling. Recycling occurs without loss of the catalytic activity after several reaction cycles.
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