期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 14, 页码 5411-5413出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo070492z
关键词
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A Sc complex of (4S,5S)-diphenyl PYBOX 1 was found to serve as a catalyst for the asymmetric conjugate addition reactions between various thiols and 3-crotonoyl-2-oxazolidinone, affording the corresponding adducts in good yields and high enantioselectivies (up to 92% ee). A new improved method for making (4S,5S)-diphenyl PYBOX is presented.
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