期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 29, 页码 8944-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0725100
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A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.
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