Influence of chain charge and complexation on the overlap and entanglements formation in poly(acrylic acid) salt-containing aqueous solutions

Dilute-semidilute regime crossover in aqueous solutions of partly neutralized poly(acrylic acid) and of its complex with tetradecyltrimethylammonium bromide was studied by light scattering and viscometry methods. The chain charge growth causes the decrease of overlap concentration (c*) and the increase of the entanglements formation concentration (c(e)), hence, the semidilute unentangled regime of solution expands. Complexation of the polyelectrolyte with an oppositely charged surfactant leads to c* increase and to c(e) decrease. It is shown that in semidilute entangled solutions the surfactant acts as an effective structuring agent because of the binding of polyelectrolyte chains via surfactant micelles.