期刊
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
卷 407, 期 1, 页码 279-284出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s00216-014-8090-3
关键词
Comprehensive two-dimensional liquid chromatography; LCxLC-MS; Surfactants; HILIC
资金
- BASF Personal Care
- Nutrition GmbH (Duesseldorf, Germany)
Comprehensive two-dimensional liquid chromatography is used to separate anionic, nonionic, and amphoteric surfactants by substance class, alkyl chain distribution, and degree of ethoxylation. A nearly orthogonal system with a hydrophilic interaction chromatography (HILIC) phase in the first and a reversed-phase material in the second dimension is applied to generate a separation with maximum peak capacity. The potential of the developed method is demonstrated by the reproducibility of retention time and peak area, which shows standard deviations less than 5 % and the analysis of real samples. An external calibration and the standard addition method were applied to determine unknown concentrations for the alkyl chain homologues of a betaine and for one ethoxylate (EO) homologue of a fatty alcohol ethoxylate in a sample mixture.
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