Lithium bis(oxalato)borate (LiBOB) salt-based nanocomposite gel polymer blend electrolyte (PVdF/PVC) membranes have been prepared by solution casting technique for various concentrations of TiO2. The effect of anatase structure of nanosized titanium dioxide in the plasticized PVC/PVdF + LiBOB matrix has been observed in the 2:1 salt filler ratio in the impedance measurements that the conductivity is increased one order of magnitude higher than the filler-free electrolyte (1:0 salt:filler ratio). The phase rnorphology of this electrolyte membrane represents the appearance of the free volume sites for ionic migration.
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