4.7 Article

Role of nitro-substituent in pseudo-polymorphism of metal carboxylato complexes of copper, zinc and in synthesis and manganese

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INORGANIC CHEMISTRY COMMUNICATIONS
卷 10, 期 8, 页码 959-964

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ELSEVIER
DOI: 10.1016/j.inoche.2007.04.026

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3d-metal carboxylates; 2-nitrobenzoato ligand; polymorphism; crystal structure; aqua-bridged complexes; paddle-wheel structure

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The consequence of nitro-group attached to aromatic ring of 2-nitrobenzoato complexes of copper(II) on pseudo-polymorphism and in synthesis of metal carboxylato complexes is demonstrated and the results are compared with analogous first row transition metal carboxylato complexes. C 2007 Elsevier B.V. All rights reserved.

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