Photopolymerization induced by a benzophenone derivative photoinitiator

A benzophenone derivative photoinitiator, HBP-TDI-HQ-TDI-HBP (HTCTH), was synthesized based on 4-hydroxy benzophenone (HBP), toluene-2,4-diisocyanate (TDI) and hydroquinone (HQ). HTCTH was a more effective photoinitiator which had longer wavelength absorption in the UV-vis absorption spectra than the low molecular counterpart benzophenone (BP). It showed that both rate of polymerization (R-p) and final conversion (P) increased with increase of amine and HTCTH concentration in photopolymerization. (c) 2007 Jun Nie. Published by Elsevier B. V. on behalf of Chinese Chemical Society. All rights reserved.